This is a common issue for me, maybe that's the same for some of you.
Say the watch is on charge and reaches 100%. I then remove the cable and open the Battery Widget to let it know it's full on battery.
During the first 1-3 hours I always see massive battery losses, like 2-4%/hr, even though my average idle discharge is 0.33%/hr.
By leaving the watch attached on charge at least 15' after 100% the problem is partially mitigated.
Did you ever encounter the same issue?